Change In Internal Energy Equation:
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The First Law of Thermodynamics states that the change in internal energy (ΔU) of a system is equal to the heat added to the system (Q) minus the work done by the system (W). This fundamental principle governs energy conservation in thermodynamic systems.
The calculator uses the internal energy equation:
Where:
Explanation: This equation represents the conservation of energy principle, where energy entering the system increases internal energy, while energy leaving decreases it.
Details: Calculating change in internal energy is essential for understanding thermodynamic processes, analyzing energy efficiency in engines and refrigeration systems, and studying chemical reactions and phase changes.
Tips: Enter heat transfer (Q) and work done (W) values in joules. Positive Q indicates heat added to the system, positive W indicates work done by the system.
Q1: What is the sign convention for Q and W?
A: Q is positive when heat is added to the system, W is positive when work is done by the system on the surroundings.
Q2: What are typical units for internal energy?
A: The SI unit is joules (J), though calories or BTUs may be used in specific contexts with appropriate conversion factors.
Q3: When is ΔU equal to zero?
A: In an isolated system or during a cyclic process where the system returns to its initial state, the net change in internal energy is zero.
Q4: How does this relate to enthalpy?
A: Enthalpy (H) is defined as H = U + PV, where P is pressure and V is volume, providing another useful thermodynamic potential.
Q5: Are there limitations to this equation?
A: This equation applies to closed systems and assumes proper accounting of all energy transfers as heat and work.